Shaman is actually pretty far beyond what most would call a "conventional" TP/TK user. He's been pegged to be on par with the Dark Phoenix, and he's incredibly hard to damage, he doesn't really have a typical flesh and blood body per se, it's actually composed of psychic energy that he has full control over. Even when his body was dispelled across the entire universe, he was still able to reform himself. So, if need be, Nate could even just fight intangible the entire time.
Additionally, Nate can actually warp space and time as well.
This would be pretty handy for Hulk's big Gamma bursts. Here; Nate warps space, and bends energy harmlessly around himself:

Nate can also casually stop time:

If need be Nate could also calm Hulk down, by making him relive his happiest memory forever:

IMO Nate would be a pretty rough match for even Hulk at this level, he's got a lot of of exotic things that he can do, he's definitely not stuck in the realm of power that most TK/TP users are in. He was even compared to Franklin Richards at one point.